In our daily lives, physical changes involve alterations in appearance or state without creating new substances, like melting ice. On the other hand, chemical changes result in the formation of entirely new substances, such as cooking food or rusting iron. Recognizing these changes helps us understand when a chemical reaction occurs.
What is Chemical reaction?
A chemical reaction is a process in which one or more substances, the Reactants, are converted to one or more different substances, the Products.
➤ The substances which take part in a chemical reaction are called Reactants.
➤ The substances which are formed in a chemical reaction are called Products.
These are the following changes to determine that the chemical reaction has taken place:
(i) Change in state : The combustion reaction of candle wax is characterised by a change in state from solid to liquid and gas.
(ii) Change in colour : Shiny brown colored Copper on heating in air becomes a black colored compound.
2Cu + O2 → 2CuO
(iii) Evolution of gas : The chemical reaction between zinc and dilute sulphuric acid is characterised by hydrogen gas.
Zn(s) + H2SO4(aq) → ZnSO4(aq) + H2(g)
(iv) Change in temperature : The reaction between quicklime and water to form slaked lime is characterised by an increase in temperature.
Ca(OH)2 + CO2 → CaCO3 + H2O
(v) Formation of a precipitate : When an aqueous solution of sodium sulphate is mixed with the aqueous solution of barium chloride, barium sulphate comes in the form of white precipitate
Na2SO4 (aq) + BaCl2(aq) → BaSO4(↓) + 2NaCl(aq)
Chemical equations
A chemical equation is a symbolic representation of a chemical reaction using the symbols and formulas of the substances involved.
For example:
Magnesium + Oxygen → Magnesium oxide
(Reactants) (Product)
The substances that undergo chemical change in the reaction, Magnesium and Oxygen, are the Reactants. When magnesium burns in air, it combines with oxygen to form magnesium oxide.
Chemical equations can be made more concise and useful if we use chemical formulae instead of words.
Example: The chemical formula for water is H2O, which indicates that it is made up of two hydrogen atoms and one oxygen atom.
Writing a chemical equation:
Representation of a chemical reaction in terms of symbols and chemical formulae of the reactants and products is known as a chemical equation.
For solids, the symbol is “(s)”.
For liquids, it is “(l)”.
For gases, it is “(g)”.
For aqueous solutions, it is “(aq)”.
For gas produced in the reaction, it is represented by “(↑)”.
For precipitate formed in the reaction, it is represented by “(↓)”.
The reactants are on the left (LHS) of the arrow, while the products are on the right (RHS). A plus sign (+) links the different reactants and products together.
Balancing the chemical Equation:
The Law of Conservation of Mass states that in a chemical reaction, atoms can't be created or destroyed. This means that the total number of atoms for each element in the starting materials (reactants) must be the same as in the end products, keeping the overall mass the same.
Example 1 :
Skeletal equation : Mg + O2 → MgO
Balanced equation : 2Mg + O2 → 2MgO
Example 2 :
Skeletal equation : Fe + H2O → Fe3O4 + H2
Balanced equation: 3Fe+ 4H2O → Fe3O4 + 4H2
Example 3 :
Skeletal equation : AgCl → Ag + Cl2
Balanced equation : 2AgCl → 2Ag + Cl2
Example 4 :
Skeletal equation : Al + O2 → Al2O3
Balanced equation : 4Al + 3O2 → 2Al2O3
→ Types of Chemical Reactions
I. Combination Reaction:
The reaction in which two or more reactants combine to form a single product.
A + B → AB
Example:
(i) Burning of coal : C + O2 → CO2
(ii) Formation of water: 2H2 + O2 → 2H2O
(iii) Calcium oxide reacts vigorously with water to produce slaked lime (calcium hydroxide) releasing a large amount of heat.
CaO + H2O → Ca(OH)2 + Heat
(Quick lime) (Slaked lime)
A solution of slaked lime produced by the reaction is used for white-washing walls. Calcium hydroxide reacts with carbon dioxide in the air to form calcium carbonate. Calcium carbonate is formed after two to three days of white washing and gives a shiny finish to the walls. It is interesting to note that the chemical formula for marble is also CaCO3.
Exothermic Reactions : Reaction in which heat is released along with formation of products.
Example:
(i) Burning of natural gas.
CH4 + 2O2 → CO2 + 2H2O + Heat
(ii) Respiration is also an exothermic reaction.
We need energy to live, and we get it from the food we eat. When we digest food, it's broken down into simpler forms. For instance, rice, potatoes, and bread have carbohydrates, which are turned into glucose. This glucose then mixes with oxygen in our cells to produce energy.
C6H12O6 + 6O2 → 6CO2 + 6H2O + energy
II. Decomposition Reaction:
The reaction in which a compound splits into two or more simpler substances is called decomposition reaction.
A → B + C
(a) Thermal decomposition:
When decomposition is carried out by heating.
Example:
Heat
(i) 2FeSO4 → Fe2O3 + SO2 + SO3
(Ferrous sulphate) (Ferric oxide)
Green colour Red-brown colour
Ferrous Sulphate Ferrous sulphate crystals (FeSO4. 7H2O) lose water when heated and the green colour of ferrous sulphate crystals fades. It then decomposes to ferric oxide (Fe203), sulphur dioxide (SO2) and sulphur trioxide (SO3). Ferric oxide is a solid, while S02 and SO3 are gases.
Heat
(ii) CaCO3 → CaO + CO2
(Lime stone) (Quick lime)
Heating calcium carbonate breaks it down into calcium oxide (lime) and carbon dioxide. This reaction is important in industries, with calcium oxide being used in cement production.
Heat
(iii) 2Pb(NO3)2 → 2PbO + 4NO2 + O2
(Lead nitrate)(Lead oxide) (Nitrogen dioxide)
Emission of brown fumes is nitrogen dioxide (NO2).
( 👉 Thermal decomposition of lead nitrate Experiment video)
(b) Electrolytic Decomposition:
When decomposition is carried out by passing electricity.
Example: Electrolysis of water
Electric current
2H2O → 2H2 + O2
★ Pure water is a bad conductor of electricity. So to carryout electrolysis it is essential to add few drops of dil. H2SO4 ,before the electrolysis
★ Gas collected at cathode is Hydrogen and at anode is Oxygen
★Water contains two parts of hydrogen element as compared to one part of oxygen element by volume. Hence, volume of gas collected at one electrode is double of another
(c) Photolytic Decomposition:
When decomposition is carried out in presence of sunlight.
Example:
(i) White silver chloride turns grey in sunlight. This is due to the decomposition of silver chloride into silver and chlorine by light.
Sunlight
2AgCl → 2Ag + Cl2
(White) (Grey)
Sunlight
(ii) 2AgBr → 2Ag + Br2
These reactions are used in black and white photography.
Endothermic Reaction: The reactions which require energy in the form of heat, light or electricity to break reactants are called endothermic reactions.
III. Displacement Reaction:
The chemical reactions in which more reactive element displaces less reactive element from its salt solution.
Example:
(i) The iron nail becomes brownish in colour and the blue colour of copper sulphate solution fades. In this reaction, iron has displaced or removed another element, copper from the copper sulphate solution.
Fe + CuSO4 → FeSO4 + Cu
(Blue) (Green)
(ii) Zinc displaces copper forming zinc sulphate. Zn is more reactive than copper.
Zn + CuSO4 → ZnSO4 + Cu
IV. Double Displacement Reaction:
A reaction in which new compounds are formed by mutual exchange of ions between two compounds.
Example:
Na2SO4 + BaCl2 → BaSO4 + 2NaCl
white precipitate of BaSO4 is formed by ther eaction of SO4^2- and Ba^2+
reaction that produces produces a precipitate can be called a precipitation reaction.
Example:
Al2(SO4)3 + 3BaCl2 → 2AlCl3 + 3BaSO4 ↓
V. Oxidation and Reduction:
Oxidation: Gain of oxygen or loss of hydrogen.
2Cu + O2 → 2CuO
Reduction: Reduction: Loss of oxygen or gain of hydrogen
Oxidation of Copper to Copper Oxide
The surface of copper powder becomes coated with black copper(ll) oxide because oxygen is added to copper and copper oxide is formed. If hydrogen gas is passed over this heated material (CuO), the black coating on the surface turns brown as the reverse reaction takes place, and copper is obtained. During this reaction, the copper(ll) oxide loses oxygen and is reduced. The hydrogen gets oxygen and is oxidized.
CuO + H2 → Cu + H2O
In this reaction, CuO is reduced to Cu and H2 is oxidised to H2O.
Redox Reaction: A reaction where one reactant is oxidised while the other is reduced.Effects of Oxidation Reaction in Everyday Life?
The process where a metal is attacked by moisture, acids, etc.
Examples:
Corrosion of iron is called rusting. Iron objects when left in moist open air for sometime get coated with a reddish brown powder. The process is known as rusting.
4Fe(s) + 3O2(from air) + xH2O(moisture) → 2Fe2O3.xH2O(rust)
Green coating on copper articles and black coating on silver ornaments are other examples of corrosion.
Cu(s) + H2O(moisture) + CO2(from air) → CuCO3.Cu(OH)2(green)
Ag(s) + H2S (from air) → Ag2S(black) + H2(g)




















