Monday, 24 February 2025

Chemistry passing package

     10th Science Most Important Repeated Concepts


                                 PASSING PACKAGE       

                                     CHEMISTRY       


  CHEMICAL REACTIONS AND EQUATIONS   

→Chemical reaction 

★ Reactant converted into product.

→ Changes in chemical reactions

★ Change in colour

★ Change in temperature

★ Change in state 

★ Evolution of gas

→Chemical equation 

★ Symbolically representation of chemical reaction. 

→Balanced chemical equation

★ Same number of atoms in LHS and RHS  

★ To follows the law of conservation of mass

Important balanced Chemical equations 

★ Hydrogen + Chlorine → Hydrogen chloride

     H2 + Cl→ 2HCl

★ Sodium + Water → Sodium hydroxide + Hydrogen.

    2Na(s) + 2H2O(l) → 2NaOH(aq) +H2(g)

★ lead nitrate is heated.

     2Pb(NO3)2 →2PbO + 4NO+ O2

★ Calcium oxide reacts with water to form slaked lime

     CaO(s) + H2O(l) → Ca(OH)2(aq) + Heat 

★ Burning of natural gas

     CH4+ 2O2 → CO2 + 2H2O

★ Calcium carbonate  → Calcium oxide + Carbon dioxide,    (Lime stone on heating)

     CaCO→ CaO + CO2

★ Magnesium + Hydrochloric acid → Magnesium chloride + Hydrogen. 

   Mg + HCl   → MgCl2 + H2

★ Sodium sulphate reacts with Barium chloride

     Na2SO+ BaCl2 → BaSO4 + 2NaCl

★ Reaction of Barium chloride with Aluminium sulphate

    BaCl2 + Al2( SO4)3 → 3BaSO4 + 2AlCl3

★ Reaction of lead with Copper Chloride

    Pb(s) + CuCl2(aq) → PbCl2(aq) + Cu(s)

★ heating of ferrous sulphate crystals.

    2FeSO4(s) → Fe2O3(s)+SO2(g)+SO3(g)

★ Zinc reacts with copper sulphate solution.

    Zn(s) + CuSO4(aq) → ZnSO4(aq) + Cu(s)

★ Zinc carbonate (s) → Zinc oxide (s)+ Carbon dioxid

    ZnCO3(s) → ZnO(s) + CO2(g)

★ Silver chloride exposed to the sunlight.

    AgCl2 → Ag + Cl2

★ H2 + O2 → H2O

    2H2 + O2 → 2H2O

★ Na2CO3 + HCl → NaCl + H2O + CO2

     Na2CO3 + 2HCl → 2NaCl + H2O + CO2

★ N2 + H2 → NH3

     N2 + 3H2→ 2NH3 

★ NaCl + AgNO3 → AgCl + NaNO3

    NaCl + AgNO3 → AgCl + NaNO3

→ Combination reactions 

 Two reactants →one product

Ex:

CaO    +     H2O   →    Ca(OH)2    +    Heat 

     (Quick lime)                 (Slaked lime)

 ➤ Burning of coal:  C + O2 → CO2

➤ Formation of water: 2H2 + O2→ 2H2O(l)

→ Decomposition reaction 

  One reactant → two or more products 

→ Thermal decomposition

➤ 2FeSO4 → Fe2O3 + SO2 + SO3

lose water when heated and the colour of the crystals changes.

➤ CaCO3 → CaO + CO2

Calcium oxide in the manufacture of cement. 

 ➤ 2Pb(NO3)2 → 2PbO + 4NO2  + O2

Emission of brown fumes are of nitrogen dioxide (NO2). 

→ Electrolytic decomposition (Electrolysis of water)

2H2O → 2H2 + O2

★ Cathode - H2

★ Anode - O2

  Photolytic decomposition

Ex: 

➤ 2AgCl     →     2Ag + Cl2 

white silver chloride turns grey in sunlight. This is due to the decomposition of silver chloride into silver and chlorine by light.

➤ 2AgBr → 2Ag + Br2

above reactions are used in black and white photography.

→ Oxidation 

★ Addition of oxygen 

Ex: 

 ➤ 2Cu + O2 → 2CuO

 ➤ 2Zn + O2 → 2ZnO

→ Reduction 

★ Removing of oxygen 

Ex: ZnO + C →Zn + CO

→ Redox reaction 

★ Oxidation and reduction occur in same reaction.

Ex: CuO + H2  →  Cu  + H2O

→ Displacement reaction 

★ More reactive element displace the less reactive element.

Ex: 

➤ Fe + CuSO4 → FeSO4    

 Iron replace the copper form copper sulphate, iron more reactive than copper.

➤ Fe2O3 + 2Al → Al2O3 + 2Fe

→ Double displacement reaction 

★ Exchange of ions between reactants.

Ex: Na2SO4 + BaCl2 → BaSO4 + 2NaCl

→ Precipitation reaction 

★  Insoluble substance formed in the reaction 

Ex: Na2SO4 + BaCl2 → BaSO4 + 2NaCl

Precipitate - BaSO4

Ions - Ba^2+ and SO4 ^ 2-

→ Exothermic reaction 

Heat released in the reaction 

Ex: 

➤ CaO + H2  Ca(OH)2   +   Heat

➤ Burning of natural gas - 

CH4 + 2O2  → CO2  + 2H2O

→ Endothermic Reaction 

Heat absorbed in the reaction 

Ex: CaCO3 →CaO + CO2

→ Corrosion 

★ Metal + atmosphere substance → Undesirable substance 

Ex: Rusting of iron  

→ Rancidity 

★ Smell /taste of oil/fat containing substance change by oxidation.

Prevention 

★ Use Antioxidant 

★ Refrigerating.

★ Use Nitrogen gas

★ Pack in air tight container 

→ Important Oxidised and Reduced reactants.

★ Na + O2 →Na2O

Oxidized substance - Na

Reduced substance - O2

★ CuO + H2 → Cu + H2O

Oxidized substance - H2

Reduced substance - CuO

★ ZnO + C → Zn + CO

Oxidized substance - C

Reduced substance - ZnO

               ACIDS, BASES AND SALTS                 

→ Acid.

★ Sour taste 

★ Produce H+ ions

★ Blue litmus to red

★ pH below 7

★ Ex: HCl, H2SO4

→Base 

★ Bitter taste 

★ Produce OH- Ions

★ Red litmus to blue 

★ pH above 7

★ Ex: NaOH, KOH,  Ca(OH)2...

→Reactions 

★ Acid + Metal → Salt + Hydrogen gas

Ex: H2SO4 + Zn → ZnSO4 + H2

★ Acid + Metal carbonate → Salt + water + Carbon dioxide 

Ex: HCl + NaHCO3 →NaCl + H2O + CO2

★ Acid + Metal oxide → Salt + Water 

2HCl + ZnO →ZnCl2 + H2O

Neutralization reaction 

★ Acid + Base →Salt + Water 

Ex: NaOH + HCl →NaCl + H2O

→ Some naturally occurring acids

★ Vinegar  - Acetic acid

★ Orange - Citric acid

★ Tamarind - Tartaric acid

★ Tomato - Oxalic acid

★ Sour milk (Curd) - Lactic acid

★ Nettle sting - Methanoic acid

★ Ant sting - Methanoic acid

★ Lemon - Citric acid

→Tooth decay 

Causes 

★ In our mouth, bacteria convert sugar into acid 

★ This acid cause tooth decay

Prevention 

★ Use toothpaste which is basic and it neutralize the acid

Blood pH: 7.2 to 7.8

Acid rain pH: below 5.6

concentrated acid: Acid with more concentration of H+ (or) larger amount of acid in less amount of water

Dilute acid: Acid with less concentration of H+ (or) less amount of acid in larger amount of water.

Strong acid: completely dissolve in water

Weak acid: incompletely dissolve in water

 → pH of Salts

​Neutral Salt: Strong Acid + Strong Base → pH is 7 (e.g., NaCl).

​Acidic Salt: Strong Acid + Weak Base → pH is < 7 (e.g., NH4Cl).

​Basic Salt: Weak Acid + Strong Base → pH is > 7 (e.g., Na2CO3).

→ Chloro alkali process 

2NaCl + 2H2O→ 2NaOH + Cl2 + H2 

Product uses:

NaOH

★ Soaps and detergents

★ Papar making 

Cl2

★ Water treatment 

★ Swimming pool

★ PVC

H2

★ Fuels

★ Margarine 

Brine solution: Aqueous solution of sodium chloride

→ Washing Soda

★ Chemical name - Sodium carbonate 

★ Chemical formula -Na2CO3

Uses 

★ Manufacture of borax, 

★ softening of hard water

→Baking Soda

★ Chemical name - Sodium hydrogen carbonate 

★ Chemical formula -NaHCO3 

Uses -

★ antacid

★ ingredient of baking powder

→ Bleaching Powder 

★ Chemical name - Calcium oxychloride 

★ Chemical formula -CaOCI2 

Uses -

★ Bleaching clothes

★ oxidizing agents

★ disinfecting water 

→ Plaster of Paris 

★ Chemical name - Calcium sulphate Hemihydrate 

★ Chemical formula -CaSO4.1/2H2

Uses -

★  Fractured bones 

★ Making toys 

★ Decorative materials

water of crystallisation: fixed number of water molecules present in one formula unit of a salt.

Ex: CuSO4.5H2O, here W.C. is 5

chemical name and formula of Marble and limestone is calcium carbonate - CaCO3

Farmer treat the soil of his field with slaked lime When acidic property of soil increases 

         𝗠𝗲𝘁𝗮𝗹𝘀 𝗮𝗻𝗱 𝗡𝗼𝗻-𝗠𝗲𝘁𝗮𝗹𝘀        

Physical properties of Metals

★ Sonorous 

★ Ductile 

★ Malleable 

★ Lustrous 

★ Conduct heat and electricity 

→ Physical Properties of Non-Metals

★ No sonorous 

★ No ductile 

★ No malleable 

★ Poor conductor of electricity 

Ductile : Metal can drawn in to thin wire. 

(most ductile metal - gold)

Malleable : Metal can beaten in to thin sheet.

→ Chemical properties of metals :

★ Liberates H2 from dilute acids.

★ Metallic oxides are basic in nature. 

★ Electro positive

→ Chemical properties of non-metals :

★ Do not liberate H2 from dilute acids. 

★ Oxides of non-metals are acidic in nature.

★ Electro negative

→ Reaction of metal with water

→ Amphoteric oxides

Metal oxides react with both acids and base give salt and water.

Ex: Al2O3 and ZnO2


→ Formation of NaCl

→ Formation of MgCl2


→ Ionic compounds
The compounds formed by the transfer of electrons from a metal to a non-metal

→ Properties 
★ Hard and brittle.               
★ High melting points and high boiling points [because strong force of attraction between ions]  
★ Soluble in water but insoluble in organic solvents.   
★ Conduct electricity in solution or molten state. [Not conduct electricity in solid state because ions are fixed cannot move]

→ Reactivity series






→ Extraction of Zn

Roasting:
                   Heat 
ZnS + O2    →    ZnO  + SO2

Calcination:
               Heat
ZnCO3    →   ZnO + CO2

Reduction:

ZnO  +  C   →  Zn  +  CO

Calcination:
                     Heating strongly 
Carbonate ore        →       Oxides 
                           Limited air
OR
Carbonate ores converted into oxides by heating strongly in presence of limited air.

Roasting:

                      Heating strongly 
Sulphide ore          →         Oxides 
                           Excess air
OR
Sulphide ores converted into oxides by heating strongly in presence of excess air.

→ Corrosion 
         Atmospheric substance
Metals            →        Undesirable substance
OR
Metals are attacked by atmospheric substances and change to Undesirable substance.
Ex: 
★ Rusting of iron 
★ Copper + Carbon dioxide → Copper carbonate 
Copper loses its brown surface and gain green coat due to formation of copper carbonate.
★ Silver + Sulfur →Silver sulphide 
Silver article become black  due to formation of silver sulphide.

→ Prevention of Corrosion 
★ Painting, 
★ Oiling, 
★ Greasing, 
★ Galvanising 
★ chrome plating, 
★ Anodising 
★ Making alloys

Galvanising: coating zinc on iron to prevent rust.

→Alloys:
Homogeneous mixer of two or more metals is called alloy.
Ex:
★ Brass : Copper and Zinc
★ Bronze : Copper and Tin
★ Solder : Lead and Tin

★ The metal that exists in liquid state at room temperature is Mercury.
★ The non metal that exists in liquid state at room temperature is Bromine.

→ Reasoning:
Metals are used in making cooking vessels, Because, metals are good conductors of heat / high melting points / malleability.

★ Sodium metal is stored in kerosene.
Because Sodium metal vigorously reacts with atmospheric oxygen and water, but not with kerosene.

★ When a calcium metal reacts with water, the liberated hydrogen gas does not catch fire.
Because The reaction of calcium with water is less violent. The heat evolved is not sufficient for the hydrogen to catch fire. 

★ Ionic compounds have high melting and boiling points. because strong force of attraction between ions.

Hydrogen gas is not liberated when a metal reacts with concentrated nitric acid. because HNO3 is a strong oxidising agent. It oxidises the H2 produced to H2O.

★ Zinc oxide is called as an amphoteric oxide. Because Zinc oxide reacts with both acids and bases to produce salt and water. 

★ Aluminium oxide is called as an amphoteric oxide. Because it reacts with both acids and bases to produce salt and water. 

★ Gold is used to make jewellery. 
Because it has properties of Lustrous, ductile, malleable and Least reactive.  

★ Ionic compounds in the solid state do not conduct electricity. Because Free ions will not form     


         𝗖𝗮𝗿𝗯𝗼𝗻 𝗔𝗻𝗱 𝗜𝘁𝘀 𝗖𝗼𝗺𝗽𝗼𝘂𝗻𝗱𝘀       

→ Covalent bond: 

Sharing of electrons between two atoms.

→ Ionic Bond:

Transfer of electrons from one atom to other.

→ Catenation:

Carbon can able to form bond with other carbon atom give large number of molecules.

→ Tetravalency: 

Carbon has 4 valency. It can bond with other carbon atoms or other than carbon atom.

→ Carbon cannot form C4+ cation 

Because of removal of 4 elections from a carbon atom would require a large amount of energy.

→ Carbon cannot form C4- anion 

Because it is difficult for the nucleus with 6 protons to hold 10 electrons.

→ Saturated hydrocarbons:
★ Single bond between two atoms.
★ Less reactive 
★ Give clean flame 
★ Ex: Alkanes (methane, Ethane, Propane..)

→ Unsaturated hydrocarbons:
★ Double / Triple bond between carbon atoms.
★ More reactive 
★ Give yellow flame 
★ Ex: Alkenes and Alkynes 

→ Alkane
★ General formula: CnH2n+2
★ First member : Methane (CH4)
★ Single bond between C atoms.

→ Alkene
★ General formula: CnH2n
★ First member : Ethene (C2H4)
★ Double  between C atoms.

→ Alkyne
★ General formula: CnH2n-2
★ First member : Ethyne (CH2)
★ Triple bond between C atoms.

→ Functional groups 

Atoms / group of atoms which given specific properties to carbon compounds.

Ex:

★ Alcohol: - OH

★ Aldehydes :     -CHO

★ Ketone :    C=O

★ Carboxylic acid:  -COOH

→ Structural isomers:

Same molecular formula but different structures are called structural isomers.

Structural isomers of butane:


→ Oxidation
Alkaline potassium permanganate or acidified potassium dichromate
 are oxidising (adding Hydrogen)  alcohols to acids

→ Addition Reaction
addition hydrogen to Unsaturated hydrocarbons  in the presence of catalysts such as palladium or nickel to give saturated hydrocarbons

→ Hydrogenation 

Conversion of unsaturated oils into saturated fats by adding hydrogen in the presence of  nickel catalyst.
Or
                                      H2
Unsaturated oil        →     Saturated fat
                                 Ni

→ Substitution reaction:

Reaction in which hydrogen atoms of a hydrocarbon are replaced by other atoms. 

Ex: CH4 + Cl2 → CH3Cl + HCl.

→ Combustion reaction:

Burning of carbon or carbon-containing compounds in the presence of air or oxygen to produce carbon dioxide, heat and light

2CH3OH + 3O2 → 4H2O + 2CO2

→ Ethanol
Uses:
★ alcoholic drinks
★ tincture iodine
★ medicines 
Reaction with sodium:
Reaction with Con. H2SO4

concentrated sulphuric acid is dehydrating agent which removes water from ethanol.

→ Ethanoic Acid (Acetic Acid)
The melting point of pure ethanoic acid
is 290 K and it freezes during winter
in cold climates hence it is called glacial
acetic acid.

→ Esterification
Formation of ester by acid and base
Acid + alcohol → esters.

Ester is Used to make perfumes and as flavouring agents.

→ Saponification
Alkaline base +  long chain carboxylic acid → soaps 

→Cleaning action of soap.
★ The ionic end of soap interacts with water while the carbon chain interacts with oil and form micelles.
★ The soap micelles pulling out the dirt from cloth.

→ Soaps 
★ Sodium salts of long chain fatty acid
★ Not give foam in hard water

→ Detergents
★ Na / K salts of sulphonic acids
★ It give foam with hard and soft water

→ Important Molecular formula and structural formula
Cyclohexane
Molecular Formula: C6H12
Structural formula:


★ Benzene 
Molecular Formula: C6H6
Structural formula: 
★ Propyne:
Molecular formula: C3H4
Structural formula:

★ Butane:
Molecular formula: C4H10
Structural formula: 


★ propanoic acid
Molecular Formula: C₃H₆O₂
Structural formula:

Pentane
Molecular formula: C5H12
Structural formula:

→ Electron dot structure:
Methane:
Oxygen:


Hydrogen:


Nitrogen:

























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